Benzyldiphenylamine → 1-(Diphenylamino)-1-phenyl-2-(1-naphthyl)ethylene

HRID 1614436Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1614436
[C:1]1([N:7]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[CH2:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1(N(C2C=CC=CC=2)/[C:28](/[C:36]2[CH:41]=[CH:40]C=CC=2)=[CH:29]/[C:30]2[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=2)C=CC=CC=1>>[C:15]1([N:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]([C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)=[CH:40][C:41]2[C:31]3[C:30](=[CH:35][CH:34]=[CH:33][CH:32]=3)[CH:29]=[CH:28][CH:36]=2)[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

Komponenten

3

Edukt 2

HCID 69080BenzyldiphenylamineHCID 10948014(E)-1-(diphenylamino)-1-phenyl-2-phenylethylene

Produkt 1

HCID 537090221-(Diphenylamino)-1-phenyl-2-(1-naphthyl)ethylene

Versuchsvorschrift

This compound was synthesized from diphenylbenzylamine and N-phenyl-1-naphthaldimine under the same conditions outlined for (E)-1-(diphenylamino)-1-phenyl-2-phenylethylene above. Recrystallization from ethyl acetate/methanol gave small crystals mp 170°-2° C. 1H NMR (200 MHz, CDCl3) δ (assignment): 6.60-6.90 (m, 2H, aromatic), 6.80-7.38 (m, 15H, aromatic), 7.52-7.85 (m, 6H, aromatic). MS [m/e (70 eV, % of base peak)] C10H7CHCPhNPh2 397 (M+., 43.1), 180 (PhCNPh+, 100), 77 (Ph+, 43.2); HRMS (m/z) for C30H23N (M+.), calcd. 397.183 found 397.195.

Aufarbeitung

  1. customRecrystallization from ethyl acetate/methanol

Quellen und Nachweise

ORD-Eintrag
ord-76607cdc89e340daa8255921075b39d5
Quelldatensatz
uspto-grants-1993_03
Patentnummer
US05196606

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