Diethyl P-((methylthio)methyl)phosphonate → HCID 23002059, Verbindung
Reaktionsgleichung
CS[CH2:3][P:4](=[O:11])([O:8][CH2:9][CH3:10])[O:5][CH2:6][CH3:7].C[O-:13].[Na+].CO>>[CH2:6]([O:5][P:4]([CH:3]=[O:13])([O:8][CH2:9][CH3:10])=[O:11])[CH3:7]Komponenten
3
Versuchsvorschrift
Oxydation of diethyl methylthiomethylphosphonate include anodic oxidation in NaOMe/MeOH (saturated with CO2) to give the O, S-acetal of diethoxyphosphinylformaldehyde, which upon oxidation may give the corresponding sulfone as Diethyl methoxy(methylsulfone)phenyl phosphonate (Shankaran, K et al. 2001).
Quellen und Nachweise
- ORD-Eintrag
- ord-d569afd160224dd8ae3fec41d4c23359
- Quelldatensatz
- uspto-grants-2014_07
- Patentnummer
- US08791235B2
Notizen zur Reaktion
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