1-Bromohexane → HCID 11732181, Verbindung

HRID 1636038Notizen

Reaktionsgleichung

[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

Komponenten

Edukt 2

HCID 81011-Bromohexane

HCID 2519872,7-Dichlorofluorene

Produkt 1

HCID 11732181HCID 11732181, VerbindungAusbeute 91 %

Versuchsvorschrift

2,7-Dichloro-9,9-di(1-hexyl)fluorene is prepared from 2,7-dichlorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C. HPLC analysis shows that the sample is 99 percent or greater pure and the spectral data confirms the title structure.

Aufarbeitung

customas colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C

Quellen und Nachweise

ORD-Eintrag: ord-e97e58c362204502aad03bd49c8da69e
Quelldatensatz: uspto-grants-2003_01
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US06512083B1

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