HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
4-Allyloxybenzoyl chloride → 7-Methacryloyloxy-2-naphthyl 4-allyloxybenzoate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 4-Allyloxybenzoyl chloride | HCID 11790137 | — |
| Edukt | 2,7-Naphthalenediol monomethacrylate | HCID 54509337 | — |
| Edukt | Hydroquinone monomethacrylate | HCID 69210285 | — |
| Lösungsmittel | Triethylamine | HCID 8471 | — |
| Produkt | 7-Methacryloyloxy-2-naphthyl 4-allyloxybenzoate | HCID 19348972 | 95% |
Reaktionsschritte
In the same way as described in Example 2, 29.5 g (0.15 mol) of 4-allyloxybenzoyl chloride and 34.5 g (0.15 mol) of 2,7-naphthalenediol monomethacrylate (obtainable in a manner similar to that of the hydroquinone monomethacrylate referred to in Example 2 of U.S. Pat. No. 4,604,342) were reacted with triethylamine as acid scavenger. 7-Methacryloyloxy-2-naphthyl 4-allyloxybenzoate, C22H20O5, with an m.p. of 85° C. was obtained in 95% yield. The 1,4-, 1,5- and 2,6-disubstituted naphthalene derivatives can be prepared in the same way.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06040411 |
| Quelldatensatz | uspto-grants-2000_03 |
| ORD ID | ord-ddcdfa0a1195484184ec68d87137acf7 |
| Quellennotiz | uspto-grants-2000_03 |