Zurück
HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1637303Erstellt: 26. Oktober 2026

4-Allyloxybenzoyl chloride → 7-Methacryloyloxy-2-naphthyl 4-allyloxybenzoate

https://huagongshe.com/reaction/1637303

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt4-Allyloxybenzoyl chlorideHCID 11790137—
Edukt2,7-Naphthalenediol monomethacrylateHCID 54509337—
EduktHydroquinone monomethacrylateHCID 69210285—
LösungsmittelTriethylamineHCID 8471—
Produkt7-Methacryloyloxy-2-naphthyl 4-allyloxybenzoateHCID 1934897295%

Reaktionsschritte

In the same way as described in Example 2, 29.5 g (0.15 mol) of 4-allyloxybenzoyl chloride and 34.5 g (0.15 mol) of 2,7-naphthalenediol monomethacrylate (obtainable in a manner similar to that of the hydroquinone monomethacrylate referred to in Example 2 of U.S. Pat. No. 4,604,342) were reacted with triethylamine as acid scavenger. 7-Methacryloyloxy-2-naphthyl 4-allyloxybenzoate, C22H20O5, with an m.p. of 85° C. was obtained in 95% yield. The 1,4-, 1,5- and 2,6-disubstituted naphthalene derivatives can be prepared in the same way.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS06040411
Quelldatensatzuspto-grants-2000_03
ORD IDord-ddcdfa0a1195484184ec68d87137acf7
Quellennotizuspto-grants-2000_03