3,5,5-Trimethylhexanal → 2,2,4,9,11,11-Hexamethyl-6-dodecanol

HRID 1638398Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1638398
BrCCC(C)CC(C)(C)C.CC(CC(C)(C)C)CC=O.[CH3:21][C:22]([CH3:46])([CH2:24][CH:25]([CH3:45])[CH2:26][CH:27]([O:37]C(N1C=NC=N1)=O)[CH2:28][CH2:29][CH:30]([CH3:36])[CH2:31][C:32]([CH3:35])([CH3:34])[CH3:33])[CH3:23]>[Cu]>[CH3:46][C:22]([CH3:23])([CH2:24][CH:25]([CH3:45])[CH2:26][CH:27]([OH:37])[CH2:28][CH2:29][CH:30]([CH3:36])[CH2:31][C:32]([CH3:35])([CH3:34])[CH3:33])[CH3:21]

Komponenten

5

Edukt 3

HCID 215743,5,5-TrimethylhexanalHCID 1428001-Bromo-3,5,5-trimethylhexaneHCID 539365921-[2,2,4,9,11,11-Hexamethyl-6-dodecyloxycarbonyl]-1,2,4-triazole

Produkt 1

HCID 197887602,2,4,9,11,11-Hexamethyl-6-dodecanol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 23978CopperKatalysator

Versuchsvorschrift

2,2,4,9,11,11-Hexamethyl-6-dodecanol (b.p. 104°-110° at 0.18 mm of mercury pressure ) was prepared by reacting 1-bromo-3,5,5-trimethylhexane with 3,5,5,-trimethylhexanal and converted into 1-[2,2,4,9,11,11-hexamethyl-6-dodecyloxycarbonyl]-1,2,4-triazole of formula: ##STR19## following the procedures of Example 18. This compound was evaluated as an extractant for copper by the procedure of Example 1 and the results are presented in Table 2.

Quellen und Nachweise

ORD-Eintrag
ord-3131b84373614cc8a9ff6c1686cd7715
Quelldatensatz
uspto-grants-1989_11
Patentnummer
US04879388

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