Methyl Palmitate → 1-Tetradecene

HRID 1639472

Reaktionsgleichung

Reaktionsgleichung von HRID 1639472
[C:1](OC)(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]CC>CCCCCC>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

Komponenten

3

Edukt 1

HCID 8181Methyl Palmitate2×

Produkt 1

HCID 142601-Tetradecene

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8058HexaneLösungsmittel

Versuchsvorschrift

Irradiation of methyl palmitate. Methyl palmitate was dissolved in a small amount of hexane and irradiated in a quartz container (UV cuvette) at 253.7 nm in the Rayonet reactor. After 7 hours a small amount of 1-tetradecene was formed. After 24 hours a larger amount of 1-tetradecene and a corresponding isomer (to be identified but likely 2-tetradecene (CH3CH═CHCH2(CH2)9CH3) was obtained.

Quellen und Nachweise

ORD-Eintrag
ord-65eed43cf6744f63b32103934bf27a48
Quelldatensatz
uspto-grants-2012_02
Patentnummer
US08110074B1

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