1,1,3,3-Tetramethyldisilazane, 97% → HCID 59227480, Verbindung
Reaktionsgleichung
[C:1]1([C:7]#[C:8][CH2:9][OH:10])[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1.[CH3:11][SiH:12]([CH3:17])N[SiH](C)C>>[C:1]1([C:7]#[C:8][CH2:9][O:10][SiH:12]([CH3:17])[CH3:11])[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1Komponenten
3
Versuchsvorschrift
3-Cyclohexenylprop-2-yn-1-ol (2.509 g, 26.10 mmol) and 1,1,3,3-tetramethyldisilazane (1.527 g, 11.45 mmol) were used according to the method mentioned above to produce the title compound as a brown clear liquid (3.916 g, 20.15 mmol, 77.2%). The crude reaction mixture was analyzed by 1H NMR to confirm the product formation and used in KOtBu catalyzed transhydrosilylation reaction.
Quellen und Nachweise
- ORD-Eintrag
- ord-dc702f953bd54bcdb9d2ccfc24939a18
- Quelldatensatz
- uspto-grants-2012_02
- Patentnummer
- US08110695B2
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