N,N-bis(1H-benzimidazol-2-ylmethyl)amine chromium (III) chloride hexafluoroantimonate tetrahydrofuran → N,N-bis(1H-benzimidazol-2-ylmethyl)-N-methylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

HRID 1645214Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1645214
[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].N1C2C=CC=CC=2N=C1CNCC1NC2C=CC=CC=2N=1.[Cl-].[Cr+3].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:55][C:56]1[NH:60][C:59]2[CH:61]=[CH:62][CH:63]=[CH:64][C:58]=2[N:57]=1)[CH2:49]CCCCC.[Cl-].[Cl-]>F[Sb-](F)(F)(F)(F)F.[Ag+].C1COCC1>[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:55][C:56]1[NH:57][C:58]2[CH:64]=[CH:63][CH:62]=[CH:61][C:59]=2[N:60]=1)[CH3:49]

Komponenten

5

Edukt 2

HCID 86638469N,N-bis(1H-benzimidazol-2-ylmethyl)amine chromium (III) chloride hexafluoroantimonate tetrahydrofuranHCID 86638471N,N-bis(1H-benzimidazol-2-ylmethyl)-N-hexylamine chromium (III) chloride

Produkt 1

HCID 86638468N,N-bis(1H-benzimidazol-2-ylmethyl)-N-methylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 16687962Silver hexafluoroantimonateKatalysatorHCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

4b was synthesised by an analogous procedure to that described for 4a using silver hexafluoroantimonate (0.661 g, 1.92 mmol) and complex 3e (1 g, 1.92 mmol). Yield 1.32 g, 87%. +FAB-MS: (m/e): 483 ([M]+), 467 ([M-Me]+), 449 ([M-Cl]), 361 ([M-Cr, Cl, THF). −FAB-MS: (m/z): 235 ([M]−).

Quellen und Nachweise

ORD-Eintrag
ord-6a647d4d20a84b88be9115cbd47872ea
Quelldatensatz
uspto-grants-2012_02
Patentnummer
US08124698B2

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