Glycolic Acid → Formate

HRID 1646712

Reaktionsgleichung

Reaktionsgleichung von HRID 1646712
[C:1]([OH:5])(=[O:4])[CH2:2][OH:3].CC1ONC(=[O:10])C=1CC(N)[C:15]([OH:17])=[O:16]>>[C:1]([O-:5])(=[O:4])[CH:2]=[O:3].[CH:15]([O-:17])=[O:16].[C:2]([O-:10])(=[O:3])[C:1]([O-:5])=[O:4]

Komponenten

5

Edukt 2

HCID 757Glycolic Acid2×HCID 1221alpha-AMINO-3-HYDROXY-5-METHYL-4-ISOXAZOLEPROPIONIC ACID

Produkt 3

HCID 283FormateHCID 71081OxalateHCID 3614358Npc324351

Versuchsvorschrift

The enzymatic oxidation of glycolic acid in Example 5 was repeated at pH 8.5, and using initial concentrations of glycolic acid and AMPA of 0.50M and 0.40M, respectively. After 16.5 h, the HPLC yields of glyoxylate, formate, and oxalate were 85.4%, 3.5%, and 6.3%, respectively, and 1.4% glycolate remained. The final pH of the reaction mixture was 7.0.

Quellen und Nachweise

ORD-Eintrag
ord-cac0e7d3df57469ca85c8d9671964b52
Quelldatensatz
uspto-grants-1993_01
Patentnummer
US05180846

Verknüpfte Notizen

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