Formaldehyde → Pentamethyldiethylenetriamine

HRID 1647351Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1647351
NC[CH2:3][NH:4][CH2:5]CN.C1O[CH:9]1[CH3:10].OC(C)[CH2:14][NH:15][CH2:16][CH2:17][NH:18][CH2:19]CN.[CH2:23]=O.[H][H]>>[CH3:23][N:18]([CH2:17][CH2:16][N:15]([CH2:9][CH2:10][N:4]([CH3:5])[CH3:3])[CH3:14])[CH3:19]

Komponenten

6

Edukt 5

HCID 712Formaldehyde2×HCID 6378Propylene Oxide2×HCID 8111Diethylenetriamine4×HCID 1700812-Propanol, 1-[[2-[(2-aminoethyl)amino]ethyl]amino]-3×HCID 178418361HCID 178418361, Verbindung2×

Produkt 1

HCID 18196Pentamethyldiethylenetriamine

Versuchsvorschrift

A one-pot reaction process for the coproduction of two polyurethane catalysts which comprises reacting excess diethylenetriamine (DETA) in a reaction vessel with propylene oxide in the presence of a hydrogenation catalyst under conditions and for a period of time to essentially completely react the propylene oxide to give a mixture of DETA and N-2-hydroxypropyldiethylenetriamine (HPDETA), adding formaldehyde and hydrogen to the reaction vessel, reacting the DETA and HPDETA with the formaldehyde and hydrogen under conditions to effect permethylation of the DETA and HPDETA to afford N,N,N',N',N"-pentamethyldiethylenetriamine (PMDETA), a polyurethane catalyst, and N-2-hydroxypropyl-N,N',N',N"-tetramethyldiethylenetriamine (HPTMDETA) a nonfugitive polyurethane catalyst.

Aufarbeitung

  1. customto give

Quellen und Nachweise

ORD-Eintrag
ord-b2204205b3c14033af0a0135e9b8db79
Quelldatensatz
uspto-grants-1995_07
Patentnummer
US05430190

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