ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate → HCID 13072040, Verbindung

HRID 1648935Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1648935
[CH2:1]([N:8]1[CH2:14][CH2:13][C:12]2[CH:15]=[C:16]([C:18]([O:20][CH2:21][CH3:22])=[O:19])[S:17][C:11]=2[CH2:10][CH2:9]1)[C:2]1C=CC=CC=1>[Ni].C(O)C>[CH2:1]([N:8]1[CH2:14][CH2:13][C:12]2[CH:15]=[C:16]([C:18]([O:20][CH2:21][CH3:22])=[O:19])[S:17][C:11]=2[CH2:10][CH2:9]1)[CH3:2]

Komponenten

4

Edukt 1

HCID 13072038ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate

Produkt 1

HCID 13072040HCID 13072040, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 935NickelKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

3.15 gm (0.01 mol) of ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate were refluxed with the same amount of Raney nickel in 50 ml of ethyl alcohol for 6 hours. The catalyst was then removed by suction filtering, and the filtrate was concentrated by evaporation.

Aufarbeitung

  1. customThe catalyst was then removed by suction
  2. filtrationfiltering
  3. concentrationthe filtrate was concentrated by evaporation

Quellen und Nachweise

ORD-Eintrag
ord-024c7012f65d4a58a5092da722aa51a2
Quelldatensatz
uspto-grants-1983_11
Patentnummer
US04414225

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