Reaktionsgleichung
[C:1]([S:8]([O:11][K])(=[O:10])=[O:9])([C:4]([F:7])([F:6])[F:5])([F:3])[F:2].[OH-].[K+].[F-].[K+]>>[C:1]([S:8]([OH:11])(=[O:9])=[O:10])([C:4]([F:5])([F:7])[F:6])([F:3])[F:2]Komponenten
4
Versuchsvorschrift
The obtained solution was heated to its boiling point until evaporation of 402 g of water, and the remaining liquid was cooled to 30° C. to cause precipitation of crystals 0.5 to 1 mm in size. The precipitate was separated by suction filtration and was dried to obtain 230 g of a crystalline powder, which consisted of 223.1 g (97.0 wt%) of C2F5SO3K, 5.5 g (2.4 wt%) of KOH and 1.4 g (0.6 wt%) of KF. Acid decomposition of this sulfonate powder and distillation of the reaction product were performed in the same manner as in Example 3. As the result C2F5SO3H of more than 99% purity was obtained.
Aufarbeitung
- distillationAcid decomposition of this sulfonate powder and distillation of the reaction product
Quellen und Nachweise
- ORD-Eintrag
- ord-09b4bdbf78c3491cab14bff79e13ec18
- Quelldatensatz
- uspto-grants-1990_05
- Patentnummer
- US04927962
Verknüpfte Notizen
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