m-Chloroperbenzoic acid → HCID 12223723, Verbindung
Reaktionsgleichung
[OH:1][CH2:2][CH2:3][N:4]1[C:24](=[O:25])[C:8]2[CH:9]=[CH:10][CH:11]=[C:12]3[S:13][C:14]4[CH:15]=[CH:16][C:17]([C:20]([F:23])([F:22])[F:21])=[CH:18][C:19]=4[N:6]([C:7]=23)[C:5]1=[O:26].ClC1C=CC=C(C(OO)=[O:35])C=1>>[OH:1][CH2:2][CH2:3][N:4]1[C:24](=[O:25])[C:8]2[CH:9]=[CH:10][CH:11]=[C:12]3[S:13](=[O:35])[C:14]4[CH:15]=[CH:16][C:17]([C:20]([F:21])([F:22])[F:23])=[CH:18][C:19]=4[N:6]([C:7]=23)[C:5]1=[O:26]Komponenten
3
Versuchsvorschrift
When 2-(2-hydroxyethyl)-10-trifluoromethyl-1H-pyrimido[5,4,3-kl]phenothiazine-1,3(2H)-dione was oxidized with m-chloroperbenzoic acid as described in the procedure of Example 6, the title compound was obtained, m.p. 205-206° (ethanol).
Quellen und Nachweise
- ORD-Eintrag
- ord-935286508ed349f3bda6debc62a91635
- Quelldatensatz
- uspto-grants-1976_06