Allyl isocyanate → 3-Ethyl-2-[O-(allylcarbamoyl) oximino]-4-thiazolidinone
Reaktionsgleichung
[CH2:1]([N:3]1[C:7](=[O:8])[CH2:6][S:5][C:4]1=[N:9][OH:10])[CH3:2].[CH2:11]([N:14]=[C:15]=[O:16])[CH:12]=[CH2:13]>C(Cl)(Cl)Cl.C(#N)C.C(N(CC)CC)C>[CH2:1]([N:3]1[C:7](=[O:8])[CH2:6][S:5][C:4]1=[N:9][O:10][C:15](=[O:16])[NH:14][CH2:11][CH:12]=[CH2:13])[CH3:2]Komponenten
6
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 3
Versuchsvorschrift
A solution of 2.0 g of 3-ethyl-2-oximino-4-thiazolidinone in 100 ml chloroform and 50 ml of acetonitrile, 1.04 g allylisocyanate and 2 drops of triethylamine was taken in a pressure bottle and left standing overnight at ambient temperature. Concentration yielded 2.6 g of product, m.p. 103°-104°.
Aufarbeitung
- waitleft
- concentrationConcentration
Quellen und Nachweise
- ORD-Eintrag
- ord-7a4e222aade048c0bc749d9d63b588c3
- Quelldatensatz
- uspto-grants-1976_06
- Patentnummer
- US03966953
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