2-Naphthyl isopropyl ketone → alpha-Bromoisopropyl 2-naphthyl ketone

HRID 1664097Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1664097
[Br-:1].[Br-].[Br-].C1([N+](C)(C)C)C=CC=CC=1.C1([N+](C)(C)C)C=CC=CC=1.C1([N+](C)(C)C)C=CC=CC=1.[CH:34]([C:37]([C:39]1[CH:48]=[CH:47][C:46]2[C:41](=[CH:42][CH:43]=[CH:44][CH:45]=2)[CH:40]=1)=[O:38])([CH3:36])[CH3:35]>O1CCCC1>[CH:40]1[C:41]2[C:46](=[CH:45][CH:44]=[CH:43][CH:42]=2)[CH:47]=[CH:48][C:39]=1[C:37]([C:34]([Br:1])([CH3:36])[CH3:35])=[O:38]

Komponenten

4

Edukt 2

HCID 109654952-Naphthyl isopropyl ketoneHCID 17977687Phenyltrimethylammonium bromide dibromide

Produkt 1

HCID 12587407alpha-Bromoisopropyl 2-naphthyl ketoneAusbeute 172,2 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

2.16 g of phenyltrimethylammonium tribromide was added to a mixture comprising 1.14 g of 2-naphthyl isopropyl ketone and 25 ml of tetrahydrofuran, and the mixture was reacted at room temperature for 3 hours. The reaction mixture was filtered, and the filtrate was concentrated under reduced pressure to obtain 1.59 g of oily α-bromoisopropyl 2-naphthyl ketone.

Aufarbeitung

  1. customthe mixture was reacted at room temperature for 3 hours
  2. filtrationThe reaction mixture was filtered
  3. concentrationthe filtrate was concentrated under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-8037e13c8f1c4a26a0fd6316a351b37f
Quelldatensatz
uspto-grants-2011_10
Patentnummer
US08039420B2

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