O-Methylhydroxylamine → HCID 19042150, Verbindung
Reaktionsgleichung
[CH3:1][O:2][NH2:3].[N+:4](/[C:7](=[CH:9]/[CH3:10])/[CH3:8])([O-:6])=[O:5]>>[CH3:1][O:2][NH:3][CH:9]([CH3:10])[CH:7]([N+:4]([O-:6])=[O:5])[CH3:8]Komponenten
3
Reaktionsbedingungen
- Temperatur
- 25 °C
Versuchsvorschrift
O-Methylhydroxylamine (176 mg, 3.75 mmol) was added to (E)-2-nitro-2-butene (303 mg, 3 mmol) and the resulting mixture was stirred at 25° C. for 10 minutes. Then, the product was isolated and purified by silica gel thin-layer chromatography (eluent: ethyl acetate/hexane=1/5). O-Methyl-N-(α-methyl-β-nitropropyl)hydroxylamine (mixture of diastereomers, yield: 95%)
Aufarbeitung
- customThen, the product was isolated
- custompurified by silica gel thin-layer chromatography (eluent: ethyl acetate/hexane=1/5)
Quellen und Nachweise
- ORD-Eintrag
- ord-dda92c8e829444fcba7ad1612c443a1c
- Quelldatensatz
- uspto-grants-1997_06
- Patentnummer
- US05639895
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