HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
1,2-Dichloroethane → Tropolone
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 1,2-Dichloroethane | HCID 11 | — |
| Edukt | 5-Amino-2-hydroxy-2,4,6-cycloheptatrien-1-one | HCID 23450 | — |
| Edukt | N-Hydroxysulfosuccinimide | HCID 133909 | — |
| Lösungsmittel | Dimethyl Sulfoxide | HCID 679 | — |
| Lösungsmittel | Carbonate Ion | HCID 19660 | — |
| Produkt | Tropolone | HCID 10789 | — |
Reaktionsschritte
To 100E6 carboxylated microspheres (previously activated with sulfo-N-hydroxysuccinimide and EDC) in 0.5 mL of carbonate buffer (pH 9) was added 2 mg of 5-aminotropolone dissolved in 25 L of dimethyl sulfoxide. The suspension was agitated for 4 hours, and the excess reagent was washed away from the microspheres.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US08153440B2 |
| Quelldatensatz | uspto-grants-2012_04 |
| ORD ID | ord-d1d6dd8a42fa4453b2d6626fd2016383 |
| Quellennotiz | uspto-grants-2012_04 |