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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1691345Erstellt: 26. Oktober 2026

(4-Phenylsulfanylmethyl-phenyl)-methanol → 4-[(Phenylsulfanyl)methyl]benzaldehyde

https://huagongshe.com/reaction/1691345

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt(4-Phenylsulfanylmethyl-phenyl)-methanolHCID 59255239—
KatalysatorHCID 178418406HCID 178418406—
LösungsmittelChloroformHCID 6212—
Produkt4-[(Phenylsulfanyl)methyl]benzaldehydeHCID 82024199,9%

Reaktionsschritte

To a chloroform (10 mL) solution of (4-phenylsulfanylmethyl-phenyl)-methanol (1 g, 4.34 mmol) described in Manufacturing Example 206-1-2 was added manganese dioxide (3.77 g, 43.4 mmol), which was stirred for 15 hours at room temperature. The manganese dioxide was removed with a Celite bed, and the filtrate was concentrated under a reduced pressure to obtain the title compound (990 mg). The title compound was used in the following reaction without any further purification.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS08153662B2
Quelldatensatzuspto-grants-2012_04
ORD IDord-8c6f1c55fa2c422c9d9c1fd949572c66
Quellennotizuspto-grants-2012_04