HCID 11109189, Verbindung → HCID 11065720, Verbindung
Reaktionsgleichung
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]1[CH2:13][C:12](=[O:14])[CH:11]=[C:10]([S:15][CH2:16][C:17](=O)[CH3:18])[CH2:9]1>C1(C)C(C)=CC=CC=1>[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]1[CH2:13][C:12](=[O:14])[C:11]2[C:17]([CH3:18])=[CH:16][S:15][C:10]=2[CH2:9]1Komponenten
3
Edukt 1
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
A solution of 5-(2-chlorophenyl)-3-(2-oxopropylthio)-2-cyclohexen-1-one (1.0 g) in xylene (10 ml) was refluxed for 7.5 days and cooled, and the reaction solution was purified with silica gel column chromatography (EtOAc/hexane) to give oil of 6-(2-chlorophenyl)-3-methyl-4,5,6,7-tetrahydrobenzothiophene-4-one (0.07 g).
Aufarbeitung
- temperaturecooled
- customthe reaction solution was purified with silica gel column chromatography (EtOAc/hexane)