HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
2-Chloroethyl chloroformate → 2-Chloroethyl 3-phenoxy-1-chloro-2-propyl carbonate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 2-Chloroethyl chloroformate | HCID 12305 | — |
| Edukt | 1-Chloro-3-phenoxy-2-propanol | HCID 94300 | — |
| Produkt | 2-Chloroethyl 3-phenoxy-1-chloro-2-propyl carbonate | HCID 20524951 | — |
Reaktionsschritte
By reacting 3-phenoxy-1-chloro-2-propanol with 2-chloroethyl chloroformate according to conventional chloroformate ester reaction procedures, 2-chloroethyl 3-phenoxy-1-chloro-2-propyl carbonate is obtained. When the latter compound is heated in the presence of a phosphonium or ammonium salt catalyst as shown in the foregoing examples, phenyl glycidyl ether is produced as the principal epoxide product.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04349482 |
| Quelldatensatz | uspto-grants-1982_09 |
| ORD ID | ord-ee227660f37a44498bf640fc72e565fe |
| Quellennotiz | uspto-grants-1982_09 |