2-Octanol → Propan-2-yl 2-dodecylbenzene-1-sulfonate

HRID 1707313

Reaktionsgleichung

Reaktionsgleichung von HRID 1707313
CC(O)CCCCCC.[CH2:10]([C:22]1C=CC=C[C:23]=1S(Cl)(=O)=O)[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]CC.[C:32]1(C)[CH:37]=[CH:36][C:35]([S:38]([O:41][CH:42]([CH3:49])[CH2:43]CCCCC)(=[O:40])=[O:39])=[CH:34][CH:33]=1>>[CH2:19]([C:34]1[CH:33]=[CH:32][CH:37]=[CH:36][C:35]=1[S:38]([O:41][CH:42]([CH3:43])[CH3:49])(=[O:39])=[O:40])[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:22][CH3:23]

Komponenten

4

Edukt 3

HCID 200832-OctanolHCID 3912199HCID 3912199, VerbindungHCID 204390012-Dodecylbenzene-1-sulfonyl chloride

Produkt 1

HCID 23368822Propan-2-yl 2-dodecylbenzene-1-sulfonateAusbeute 83 %

Versuchsvorschrift

In Example of preparation of material 15, 2-octanol was used in place of 2-propanol in Example of preparation of material 14. In Example of preparation of material 16, dodecylbenzene sulfonyl chloride was used in place of p-toluene sulfonyl chloride in Example of preparation of material 14. Other procedures were made in the same way as Example of preparation of material 14. In Example of preparation of material 15, 1-methylheptyl p-toluenesulfonate was obtained in the yield of 72% and, in Example of preparation of material 16, 1-methylethyl dodecylbenzene sulfonate was obtained in the yield of 83%.

Quellen und Nachweise

ORD-Eintrag
ord-58dd63a5933b4544b12d862b35b14947
Quelldatensatz
uspto-grants-1994_10
Patentnummer
US05352740

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