HCID 13318009, Verbindung → HCID 23039203, Verbindung
Reaktionsgleichung
COC(=O)CN(C(C1C2C(=C(Br)C=CC=2)C=CC=1)=S)C.C([O:23][C:24](=[O:42])[CH2:25][NH:26][C:27]([C:29]1[C:38]2[C:33](=[CH:34][CH:35]=[CH:36][CH:37]=2)[C:32]([O:39][CH3:40])=[C:31]([Cl:41])[CH:30]=1)=[S:28])C>>[Cl:41][C:31]1[CH:30]=[C:29]([C:27](=[S:28])[NH:26][CH2:25][C:24]([OH:42])=[O:23])[C:38]2[C:33]([C:32]=1[O:39][CH3:40])=[CH:34][CH:35]=[CH:36][CH:37]=2Komponenten
3
Versuchsvorschrift
In the same manner, but replacing N-[(5-bromo-1-naphthalenyl)thioxomethyl]-N-methylglycine methyl ester with an equivalent amount of N-[(3-chloro-4-methoxy-1-naphthalenyl)thioxomethyl]glycine ethyl ester, described in Example 31, N-[(3-chloro-4-methoxy-1-naphthalenyl)thioxomethyl]glycine [mp 217° C. (dec); NMR(DMSO-d6) δ3.96 (s, 3H), 4.42 (d, J=6 Hz, 2H), 7.40 (s, 1H), 7.65 (m, 2H), 8.18 (m, 2H); IR (Nujol *) 3150, 2900, 1720, 1140 cm-1 ; UVλmax (EtOH) 277 nm (ε11,400), 224 (51,300); Anal Calcd: C, 54.28% H, 3.91% N, 4.52%; Found: C, 54.26% H, 4.06% N, 4.62%] was obtained.
Quellen und Nachweise
- ORD-Eintrag
- ord-16c93c22bf144aa6bdea4b4e44b2b9da
- Quelldatensatz
- uspto-grants-1990_08