1,3-Dimethyl-2-imidazolidinone → 3-Phenoxybenzyl alcohol
Reaktionsgleichung
CN1CCN(C)[C:3]1=[O:8].Cl[C:10]1[CH:11]=[C:12](C(C)(C)CCl)[CH:13]=[CH:14][C:15]=1[O:16][CH2:17][CH3:18]>>[O:16]([C:15]1[CH:10]=[C:11]([CH:12]=[CH:13][CH:14]=1)[CH2:3][OH:8])[C:17]1[CH:18]=[CH:14][CH:15]=[CH:10][CH:11]=1Komponenten
3
Versuchsvorschrift
3 l (3,156 g) of 1,3-dimethyl-2-imidazolidinone (hereinafter referred to as DMI), 618.0 g (2.50 mol) of purified 2-(3-chloro-4-ethoxyphenyl)-2-methylpropyl chloride obtained in the same manner as in Example 1, 1,251.0 g (6.25 mol) of m-phenoxybenzyl alcohol (a product of Ethyl Corp.) and 280.0 g (5.00 mol) of potassium hydroxide in the form of flakes were charged in a 5 l four-neck flask and stirred at 120° C. under nitrogen stream for 15 h to complete the reaction.
Quellen und Nachweise
- ORD-Eintrag
- ord-e98a9814729042de9c6966ebdf21f885
- Quelldatensatz