1,3-Butanediol → (-)-1,3-Butanediol

HRID 1721560

Reaktionsgleichung

Reaktionsgleichung von HRID 1721560
[CH3:1][O:2][P:3]([O:7]/[C:8](/[C:11]1[C:16]([Cl:17])=[CH:15][C:14]([Cl:18])=[C:13]([Cl:19])[CH:12]=1)=[CH:9]\[Cl:10])([O:5][CH3:6])=[O:4].[CH2:20]([OH:25])[CH2:21][CH:22]([OH:24])[CH3:23]>>[CH2:20]([OH:25])[CH2:21][C@H:22]([OH:24])[CH3:23].[CH3:6][O:5][P:3]([O:7]/[C:8](/[C:11]1[C:16]([Cl:17])=[CH:15][C:14]([Cl:18])=[C:13]([Cl:19])[CH:12]=1)=[CH:9]\[Cl:10])([O:2][CH3:1])=[O:4]

Komponenten

4

Edukt 2

HCID 78961,3-ButanediolHCID 5284462Tetrachlorvinphos

Produkt 2

HCID 637497(-)-1,3-ButanediolHCID 5284462Tetrachlorvinphos

Versuchsvorschrift

The microorganisms usable in the present invention include those belonging to the genera Rhodococcus, Gordona and Streptomyces and capable of acting on an enantiomorphic mixture of 1,3-butanediol so as to leave (R)-1,3-butanediol as such and those belonging to the genera Rhodococcus and Gordona capable of acting on an enantiomorphic mixture of 1,3-butanediol so as to leave (S)-1,3-butanediol as such.

Quellen und Nachweise

ORD-Eintrag
ord-90c9f39d72244ded83edeafd5065156e
Quelldatensatz
uspto-grants-1996_04
Patentnummer
US05512465

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