Tributylstannane → 1-(tributylstannyl)-1E-undecen-3-ol

HRID 1722344Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1722344
[CH:1]#[C:2][CH:3]([OH:12])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([SnH:17]([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:18][CH2:19][CH2:20][CH3:21])[CH2:14][CH2:15][CH3:16]>>[CH2:22]([Sn:17]([CH2:13][CH2:14][CH2:15][CH3:16])([CH2:18][CH2:19][CH2:20][CH3:21])/[CH:1]=[CH:2]/[CH:3]([OH:12])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:23][CH2:24][CH3:25]

Komponenten

3

Edukt 2

HCID 5948TributylstannaneHCID 2477661-Undecyn-3-ol

Produkt 1

HCID 121582911-(tributylstannyl)-1E-undecen-3-ol

Reaktionsbedingungen

Temperatur
120 °C

Versuchsvorschrift

To 0.07g (0.42 mmol) of the titled product of Example 7 is added 0.15g (0.5 mmol) of tri-n-butyltin hydride and 20mg of azoisobutyronitrile (AIBN). The reaction mixture was heated to 120°C. for 2 hours. Afterwards, it was cooled to room temperature and pumped at high vacuum overnight. The crude reaction mixture was then heated to 90°C. and maintained at high vacuum for 2 additional hours. Upon cooling to room temperature, the crude product was used as is.

Aufarbeitung

  1. temperatureAfterwards, it was cooled to room temperature
  2. custompumped at high vacuum overnight
  3. customThe crude reaction mixture
  4. temperaturewas then heated to 90°C.
  5. temperaturemaintained at high vacuum for 2 additional hours
  6. temperatureUpon cooling to room temperature

Quellen und Nachweise

ORD-Eintrag
ord-167ca511f3a94596a51c3ca4c0590847
Quelldatensatz
uspto-grants-1989_08
Patentnummer
US04855324

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