2,6-Dipropylphenol → 2,6-Dipropyl4-propionylphenol

HRID 1727286Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1727286
[C:1]([O-:5])(=O)[CH2:2][CH3:3].[Na+].[CH2:7]([C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([CH2:16][CH2:17][CH3:18])[C:11]=1[OH:19])[CH2:8][CH3:9]>OS(C(F)(F)F)(=O)=O>[CH2:16]([C:12]1[CH:13]=[C:14]([C:1](=[O:5])[CH2:2][CH3:3])[CH:15]=[C:10]([CH2:7][CH2:8][CH3:9])[C:11]=1[OH:19])[CH2:17][CH3:18]

Komponenten

4

Edukt 2

HCID 811072,6-DipropylphenolHCID 2723816Sodium Propionate

Produkt 1

HCID 113108722,6-Dipropyl4-propionylphenol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 62406Trifluoromethanesulfonic acidLösungsmittel

Versuchsvorschrift

Sodium propanoate (0.88 g, 1.5 eq) and 2,6-dipropylphenol (1.09 g, 1.0 eq) were combined in Triflic Acid (5.0 g) as in Example 13, step 1. The resulting waxy solid was purified by chromatography on silica gel using ethyl acetate:hexanes:acetic acid (10:90:1) to give the titled phenol.

Aufarbeitung

  1. customThe resulting waxy solid was purified by chromatography on silica gel

Quellen und Nachweise

ORD-Eintrag
ord-3b0334179b264f1582ed15228403292d
Quelldatensatz
uspto-grants-2009_02
Patentnummer
US07495020B2

Notizen zur Reaktion

Wird geladen…