Dihydrodiethylstilbestrol → Hexestrol

HRID 1729932

Reaktionsgleichung

Reaktionsgleichung von HRID 1729932
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([CH:11]([C:14]2[CH:19]=[CH:18][C:17]([OH:20])=[CH:16][CH:15]=2)[CH2:12][CH3:13])[CH2:9][CH3:10])=[CH:4][CH:3]=1.OC1C=CC(C(C2C=CC(O)=CC=2)(CC)CC)=CC=1.OC1C=CC(C(C2C=CC(O)=CC=2)(C)C)=CC=1.OC1C=CC(C2(C3C=CC(O)=CC=3)C=CC=CC2C=C)=CC=1.C(C1C=C(O)C=CC=1CCC1C=CC(O)=CC=1CC)C.C(C1C(O)=CC=CC=1CCC1C=CC=C(O)C=1CC)C.C/C=C(\C1C=CC(O)=CC=1)/C(/C1C=CC(O)=CC=1)=C/C.OC1C=CC(C(CC(C2C=CC(O)=CC=2)CC)CC)=CC=1.OC1C=CC(CCCCC2C=CC(O)=CC=2)=CC=1.OC1C=CC(CCCC2C=CC(O)=CC=2)=CC=1.FC1C=C(C(C2C=CC(O)=C(F)C=2)(C)C)C=CC=1O>>[CH3:13][CH2:12][C@@H:11]([C@H:8]([C:5]1[CH:4]=[CH:3][C:2]([OH:1])=[CH:7][CH:6]=1)[CH2:9][CH3:10])[C:14]1[CH:19]=[CH:18][C:17]([OH:20])=[CH:16][CH:15]=1

Komponenten

12

Edukt 11

HCID 3606DihydrodiethylstilbestrolHCID 6623Bisphenol AHCID 2578314,4'-Propane-1,3-diyldiphenolHCID 667476DienestrolHCID 22885033,3-Bis(4-hydroxyphenyl)pentaneHCID 14317738HCID 14317738, VerbindungHCID 214020871,2-Bis(2-ethyl-4-hydroxyphenyl)ethaneHCID 218963052,2-Bis (3-fluoro-4-hydroxyphenyl) propaneHCID 856348173,5-Bis(4-hydroxyphenyl) heptaneHCID 867341312,2-Bis(4-hydroxyphenyl) styreneHCID 867341321,2-Bis(2-ethyl-3-hydroxyphenyl) ethane

Produkt 1

HCID 192197Hexestrol

Versuchsvorschrift

3,4-bis(4-hydroxyphenyl) hexane; 3,3bis(4-hydroxyphenyl)pentane; 2,2-bis(4-hydroxyphenyl) propane; 2,2-bis(4-hydroxyphenyl) styrene; 1,2-bis(2-ethyl-4-hydroxyphenyl)ethane, 1,2-bis(2-ethyl-3-hydroxyphenyl) ethane; dienestrol (3,4-bis(4-hydroyphenyl)-2,4-hexadiane); 3,5-bis(4-hydroxyphenyl) heptane; 1,4-bis(4-hydroxyphenyl)-butane, 1,3-bis(4-hydroxyphenyl) propane, 2,2-bis (3-fluoro-4-hydroxyphenyl) propane, 2,2-bis(4-hydroxyphenyl)-3'-methyl styrene, 2,2-bis(4-hydroxyphenyl)-4'-fluorostyrene and 2,2bis(4-hydroxyphenyl)-4'-trifluoromethyl styrene.

Quellen und Nachweise

ORD-Eintrag
ord-b4d452d7b67b4e5c9838422db26e5aea
Quelldatensatz
uspto-grants-1976_11
Patentnummer
US03989825

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