Sodium Hydroxide → Copper oleate
Reaktionsgleichung
[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[OH-].[Na+].[Cu:23]>>[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[Cu+2:23].[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]Komponenten
4
Versuchsvorschrift
To the reaction flask was charged 27.64 g (0.100 mole) of oleic acid, 10.0 g of mineral spirits and 80.0 g of 0.1N sodium hydroxide. A copper rod was used as the anode and a graphite rod as the cathode. 6,496 coulombs of electricity were passed and 2.30 g (0.030 mole) of copper was consumed. After isolation of the product, a green solution of copper oleate in mineral spirits containing 6% copper was obtained.
Quellen und Nachweise
- ORD-Eintrag
- ord-4f81d39a6fa44e588d5006b8ff41b9c0