Methanesulfonate → 4-Methoxy-4-(3-methanesulfonyl-trans-prop-1-enyl)tetrahydropyran

Reaktionsgleichung

[CH3:1][O:2][C:3]1(/[CH:9]=[CH:10]/[CH2:11]O)[CH2:8][CH2:7][O:6][CH2:5][CH2:4]1.[S:13]([O-])(=[O:16])(=[O:15])[CH3:14]>>[CH3:1][O:2][C:3]1(/[CH:9]=[CH:10]/[CH2:11][S:13]([CH3:14])(=[O:16])=[O:15])[CH2:8][CH2:7][O:6][CH2:5][CH2:4]1

Komponenten

Edukt 2

HCID 85257Methanesulfonate

HCID 151990644-Methoxy-4-(3-hydroxy-trans-prop-1-enyl)tetrahydropyran

Produkt 1

HCID 193880264-Methoxy-4-(3-methanesulfonyl-trans-prop-1-enyl)tetrahydropyran

Versuchsvorschrift

4-methoxy-4-(3-hydroxy-trans-prop-1-enyl)tetrahydropyran, prepared as in step 4, was convened to the corresponding mesylate according to the methodof Crossland and Servis, J. Org. Chem., 35, 3195-3196 (1970).

Quellen und Nachweise

ORD-Eintrag: ord-0bd9f81c06d847f6a4dd727660b65f6a
Quelldatensatz: uspto-grants-1995_08
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05446062

Notizen zur Reaktion

Wird geladen…