HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
(3-Phenoxy-phenyl)-2-propyn-1-yl alcohol → 2,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | (3-Phenoxy-phenyl)-2-propyn-1-yl alcohol | HCID 53853920 | — |
| Edukt | 2,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid | HCID 54570584 | — |
| Lösungsmittel | Chloroform | HCID 6212 | — |
| Produkt | 2,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid | HCID 54570584 | — |
| Produkt | 2,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylate | HCID 73655273 | — |
Reaktionsschritte
Using the procedure of Example 9, (1R, cis, ΔZ) 2,2-dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid and 1R (3-phenoxy-phenyl)-2-propyn-1-yl alcohol were reacted to obtain 1R (3-phenoxy-phenyl)-2-propyn-1-yl (1R, cis, ΔZ) 2,2-dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylate with a specific roation of [α]D20 =+48°±2° (c=1% in chloroform).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04833163 |
| Quelldatensatz | uspto-grants-1989_05 |
| ORD ID | ord-dfd29c4a7898454f80fc2cf4d64f1736 |
| Quellennotiz | uspto-grants-1989_05 |