HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
3-Phenoxybenzyl alcohol → 2,2-Dimethyl-3-(3-cyclopropylmethoxy-3-oxo-1-propenyl) cyclopropane-carboxylic acid
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 3-Phenoxybenzyl alcohol | HCID 26295 | — |
| Edukt | 2,2-Dimethyl-3-(3-cyclopropylmethoxy-3-oxo-1-propenyl) cyclopropane-carboxylic acid | HCID 53915596 | — |
| Lösungsmittel | Chloroform | HCID 6212 | — |
| Produkt | 2,2-Dimethyl-3-(3-cyclopropylmethoxy-3-oxo-1-propenyl) cyclopropane-carboxylic acid | HCID 53915596 | — |
| Produkt | 2,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylate | HCID 73655273 | — |
Reaktionsschritte
Using the procedure of Example 9, m-phenoxy-benzyl alcohol and (1R, cis, ΔZ) 2,2-dimethyl-3-(3-n-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid were reacted to obtain m-phenoxy-benzyl (1R, cis, ΔZ) 2,2-dimethyl-3-(3-n-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylate with a specific rotation of [α]D20 =+40°±2° (c=0.5% in chloroform).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04833163 |
| Quelldatensatz | uspto-grants-1989_05 |
| ORD ID | ord-a295e9bd46054b8584f325ec49e09cb5 |
| Quellennotiz | uspto-grants-1989_05 |