Sodium Hydroxide → HCID 14623875, Verbindung

HRID 1781254Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1781254
[O:1]=[C:2]1[CH2:5][C:4]([C:11]([O:13]CC)=[O:12])([C:6]([O:8]CC)=[O:7])[NH:3]1.[OH-].[Na+:17]>CO>[O:1]=[C:2]1[CH2:5][C:4]([C:6]([O-:8])=[O:7])([C:11]([O-:13])=[O:12])[NH:3]1.[Na+:17].[Na+:17]

Komponenten

4

Edukt 2

HCID 14798Sodium HydroxideHCID 19045180HCID 19045180, Verbindung

Produkt 1

HCID 14623875HCID 14623875, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

1(c) 5.72 g of diethyl 2-oxoazetidine-4,4-dicarboxylate (prepared as described above) were dissolved in 25 ml of methanol. 53.2 ml of a 1N aqueous solution of sodium hydroxide were added to the resulting solution, and the mixture was stirred at room temperature for 1 day. At the end of this time, the reaction mixture was concentrated by evaporation under reduced pressure to give crystals, which were washed with methanol and with diethyl ether to give 5.3 g of the title compound as crystals.

Aufarbeitung

  1. concentrationAt the end of this time, the reaction mixture was concentrated by evaporation under reduced pressure
  2. customto give crystals, which
  3. washwere washed with methanol and with diethyl ether

Quellen und Nachweise

ORD-Eintrag
ord-70e6a23c877648c4afd2e249917b361d
Quelldatensatz
uspto-grants-1997_05
Patentnummer
US05633243

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