Methyl 1-ethyl-5-(4-chlorobenzoyl)oxindole-3-carboxylate → Ethyl 1-ethyl-5-benzoyloxindole-3-carboxylate

HRID 1788954

Reaktionsgleichung

Reaktionsgleichung von HRID 1788954
[CH2:1]([N:3]1[C:11]2[C:6](=[CH:7][C:8]([C:12](=[O:20])[C:13]3[CH:18]=[CH:17][C:16](Cl)=[CH:15][CH:14]=3)=[CH:9][CH:10]=2)[CH:5]([C:21]([O:23][CH3:24])=[O:22])[C:4]1=[O:25])[CH3:2].[CH2:26](N1C2C(=CC(C(=O)C3C=CC(F)=CC=3)=CC=2)C(C(OC)=O)C1=O)C.C(N1C2C(=CC(C(=O)C3C=CC(C)=CC=3)=CC=2)C(C(OC)=O)C1=O)C>>[CH2:1]([N:3]1[C:11]2[C:6](=[CH:7][C:8]([C:12](=[O:20])[C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)=[CH:9][CH:10]=2)[CH:5]([C:21]([O:23][CH2:24][CH3:26])=[O:22])[C:4]1=[O:25])[CH3:2]

Komponenten

4

Edukt 3

HCID 13934855Methyl 1-ethyl-5-(4-chlorobenzoyl)oxindole-3-carboxylateHCID 13934856Methyl 1-ethyl-5-(4-fluorobenzoyl)oxindole-3-carboxylateHCID 13934857Methyl 1-ethyl-5-(4-methylbenzoyl)oxindole-3carboxylate

Produkt 1

HCID 20189466Ethyl 1-ethyl-5-benzoyloxindole-3-carboxylate

Versuchsvorschrift

In a similar manner were prepared methyl 1-ethyl-5-(4-chlorobenzoyl)oxindole-3-carboxylate, m.p. 115°-118° C.; methyl 1-ethyl-5-(4-fluorobenzoyl)oxindole-3-carboxylate, m.p. 90°-100° C. (dec.); and methyl 1-ethyl-5-(4-methylbenzoyl)oxindole-3carboxylate, m.p. 110°-115° C.

Quellen und Nachweise

ORD-Eintrag
ord-ee6eca94548940528bfcb2b9ba4a3f66
Quelldatensatz
uspto-grants-1987_08
Patentnummer
US04686224

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