Nitric Acid → 2-Nitro-4-n-butoxy-5-methoxybenzonitrile

HRID 1801478

Reaktionsgleichung

Reaktionsgleichung von HRID 1801478
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:8]=[CH:9][C:10]=1[O:11][CH2:12][CH2:13][CH2:14][CH3:15])[C:6]#[N:7].[N+:16]([O-])([OH:18])=[O:17]>>[N+:16]([C:8]1[CH:9]=[C:10]([O:11][CH2:12][CH2:13][CH2:14][CH3:15])[C:3]([O:2][CH3:1])=[CH:4][C:5]=1[C:6]#[N:7])([O-:18])=[O:17]

Komponenten

3

Edukt 2

HCID 944Nitric AcidHCID 44587574-Butoxy-3-methoxybenzonitrile

Produkt 1

HCID 583678172-Nitro-4-n-butoxy-5-methoxybenzonitrile

Reaktionsbedingungen

Temperatur
30 °C

Versuchsvorschrift

3-methoxy-4-n-butoxybenzonitrile (1.282 g, 6 mmol) and nitric acid (6 mL) were added into a round bottom flask, heated to 30° C. to react for 2 h, poured into ice-water; after complete stirring, the solution was filtered, washed with water and air-dried to yield 1.495 g of light yellow solid product with a recovery rate of 96%.

Aufarbeitung

  1. customto react for 2 h
  2. filtrationafter complete stirring, the solution was filtered
  3. washwashed with water
  4. customair-dried

Quellen und Nachweise

ORD-Eintrag
ord-4be8465a9a8e4f788b126a6aa277adbf
Quelldatensatz
uspto-grants-2013_01
Patentnummer
US08349835B2

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