Potassium Carbonate → Ethyl 4-(benzyloxy)-3-hydroxybenzoate

HRID 1810918Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1810918
[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([O:19]C(=O)C)[CH:6]=1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([OH:19])[CH:6]=1)[CH3:2]

Komponenten

4

Edukt 2

HCID 11430Potassium CarbonateHCID 67170201HCID 67170201, Verbindung

Produkt 1

HCID 11311797Ethyl 4-(benzyloxy)-3-hydroxybenzoate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

The compound of step 1 (10 g, 31.8 mmol) was dissolved in methanol, potassium carbonate (88 mg, 0.636 mmol) was added and the mixture was stirred for 2 h under reflux. After evaporation to dryness, the residue was used without further purification in the subsequent step.

Aufarbeitung

  1. temperatureunder reflux
  2. customAfter evaporation to dryness
  3. customthe residue was used without further purification in the subsequent step

Quellen und Nachweise

ORD-Eintrag
ord-847ccc0412f24323a43d8dcb4df6878b
Quelldatensatz
uspto-grants-2013_01
Patentnummer
US08362073B2

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