Ammonium Acetate → 9-Aminospiro[4.5]dec-8-EN-7-one

HRID 1817807

Reaktionsgleichung

Reaktionsgleichung von HRID 1817807
CN(C)[C:3]1[CH:8]=[CH:7][C:6]([CH:9]2[CH2:14][C:13](=[O:15])[CH2:12][C:11](=O)[CH2:10]2)=CC=1.C1C2(CC(=O)CC(=O)C2)CCC1.C([O-])(=O)C.[NH4+:34]>>[NH2:34][C:11]1[CH2:10][C:9]2([CH2:6][CH2:7][CH2:8][CH2:3]2)[CH2:14][C:13](=[O:15])[CH:12]=1

Komponenten

4

Edukt 3

HCID 517165Ammonium AcetateHCID 7301175-(4-(Dimethylamino)phenyl)-1,3-cyclohexanedioneHCID 4831594Spiro[4.5]decane-7,9-dione

Produkt 1

HCID 578832909-Aminospiro[4.5]dec-8-EN-7-one

Versuchsvorschrift

In analogy to (Baraldi, P. G.; Simoni, D.; Manfredini, S.; Synthesis 1983, (11) 902-903 spiro[4.5]decane-7,9-dione was reacted with ammonium acetate to give the title compound as a colorless solid.

Quellen und Nachweise

ORD-Eintrag
ord-6175484f394d4eb691a663225203d72e
Quelldatensatz
uspto-grants-2009_10
Patentnummer
US07598384B2

Verknüpfte Notizen

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