2-Aminomethyl-4,4,8-trimethyl-nonanoic acid → 2-Aminomethyl-4-ethyl-8-methyl-nonanoic Acid

Reaktionsgleichung

[NH2:1][CH2:2][CH:3]([CH2:7][C:8]([CH3:16])(C)[CH2:9][CH2:10][CH2:11][CH:12]([CH3:14])[CH3:13])[C:4]([OH:6])=[O:5].N[CH2:18]C(CCCCCC(C)C)C(O)=O.C1(C(OC2C(C(C)(C)C)=CC(C)=CC=2C(C)(C)C)=O)CC1>>[NH2:1][CH2:2][CH:3]([CH2:7][CH:8]([CH2:16][CH3:18])[CH2:9][CH2:10][CH2:11][CH:12]([CH3:13])[CH3:14])[C:4]([OH:6])=[O:5]

Komponenten

Edukt 3

HCID 103079982-Aminomethyl-4,4,8-trimethyl-nonanoic acid

HCID 13676039Cyclopropanecarboxylic acid 2,6-di-tert-butyl-4-methyl-phenyl ester

HCID 219434912-Aminomethyl-8-methyl-nonanoic acid

Produkt 1

HCID 102361372-Aminomethyl-4-ethyl-8-methyl-nonanoic Acid

Versuchsvorschrift

A procedure similar to that of 2-Aminomethyl-4,4,8-trimethyl-nonanoic acid was utilized to prepare 2-Aminomethyl-8-methyl-nonanoic acid from 2,6-di-t-butyl-4-methylphenyl cyclopropylcarboxylate. m/z 230.2 (M+).

Quellen und Nachweise

ORD-Eintrag: ord-fdbf83bf0b104174ab3b8caf8159cab8
Quelldatensatz: uspto-grants-2006_06
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US07064147B2

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