8-Methylsulfonyl-12-hydroxy-13,13-dimethyl-10-heptadecynoic acid → 8-Methylsulfonyl-12-hydroxy-13,13-dimethylheptadecanoic acid
Reaktionsgleichung
CS(C(CC#C[C@@H](O)CCCCC)CCCCCCC(O)=O)(=O)=O.[CH3:25][S:26]([CH:29]([CH2:39][C:40]#[C:41][CH:42]([OH:50])[C:43]([CH3:49])([CH3:48])[CH2:44][CH2:45][CH2:46][CH3:47])[CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][C:36]([OH:38])=[O:37])(=[O:28])=[O:27]>>[CH3:25][S:26]([CH:29]([CH2:39][CH2:40][CH2:41][CH:42]([OH:50])[C:43]([CH3:49])([CH3:48])[CH2:44][CH2:45][CH2:46][CH3:47])[CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][C:36]([OH:38])=[O:37])(=[O:27])=[O:28]Komponenten
3
Versuchsvorschrift
The synthesis of this compound is carried out by hydrogenation exactly as described in Example 15 except that 8-methylsulfonyl-12(S)-hydroxy-10-heptadecynoic acid is replaced by an equivalent quantity of 8-methylsulfonyl-12-hydroxy-13,13-dimethyl-10-heptadecynoic acid.
Aufarbeitung
- customThe synthesis of this compound