Carbon Disulfide → (2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid

HRID 1834549

Reaktionsgleichung

Reaktionsgleichung von HRID 1834549
[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH2:11].[C:12](=[S:14])=[S:13]>C(O)C>[CH3:1][C:2]1[NH:3][CH:4]=[N:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH:11][C:12](=[S:13])[SH:14]

Komponenten

4

Edukt 2

HCID 6348Carbon DisulfideHCID 178433288HCID 178433288, Verbindung

Produkt 1

HCID 15566013(2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

A solution of 4-methyl-5-((2-aminoethyl)thiomethyl) imidazole (10.2 g) in ethanol(75 ml) was added slowly, with stirring, to carbon disulphide (200 ml). The mixture was set aside overnight at room temperature and the solid formed was collected and recystallised from aqueous isopropyl alcohol to afford N-[2-((5-methyl-4imidazolyl)methylthio)ethyl]dithiocarbamic acid (9.8 g)., m.p. 127°-129°.

Aufarbeitung

  1. customthe solid formed
  2. customwas collected

Quellen und Nachweise

ORD-Eintrag
ord-4c908ea815e94302afee9727e4d82d92
Quelldatensatz
uspto-grants-1978_01
Patentnummer
US04070472

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