Hydroxyacetonitrile → N-carboxymethyl-N-cyanomethylamino-2-ethanol
Reaktionsgleichung
[C:1]([CH2:4][NH:5][CH2:6][CH2:7][OH:8])([OH:3])=[O:2].[C:9](#[N:12])[CH2:10]O>>[C:1]([CH2:4][N:5]([CH2:6][CH2:7][OH:8])[CH2:10][C:9]#[N:12])([OH:3])=[O:2]Komponenten
3
Versuchsvorschrift
The hydrolysis of (I) with base gives N-carboxymethylamino-2-ethanol (II). Compound (II) is then reacted with additional glycolonitrile to form N-carboxymethyl-N-cyanomethylamino-2-ethanol (III). The molar ratio of (II) to glycolonitrile is generally about 1:1. In the above reactions, hydrogen cyanide and formaldehyde can be substituted for glycolonitrile.
Quellen und Nachweise
- ORD-Eintrag
- ord-2bfdd368208a447a97e7268f9780631d
- Quelldatensatz
- uspto-grants-1998_03
- Patentnummer
- US05726341
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