2-(tert-Butyl)-5-nitro-1H-indole → (R)-N-(2-tert-butyl-1-(2,3-dihydroxypropyl)-1H-indol-5-yl)-1-(3,4-dihydroxyphenyl)cyclopropanecarboxamide
Reaktionsgleichung
[OH:1][C:2]1[CH:3]=[C:4]([C:9]2([C:12]([OH:14])=O)[CH2:11][CH2:10]2)[CH:5]=[CH:6][C:7]=1[OH:8].[C:15]([C:19]1[NH:20][C:21]2[C:26]([CH:27]=1)=[CH:25][C:24]([N+:28]([O-])=O)=[CH:23][CH:22]=2)([CH3:18])([CH3:17])[CH3:16]>>[C:15]([C:19]1[N:20]([CH2:3][C@@H:2]([OH:1])[CH2:7][OH:8])[C:21]2[C:26]([CH:27]=1)=[CH:25][C:24]([NH:28][C:12]([C:9]1([C:4]3[CH:5]=[CH:6][C:7]([OH:8])=[C:2]([OH:1])[CH:3]=3)[CH2:10][CH2:11]1)=[O:14])=[CH:23][CH:22]=2)([CH3:18])([CH3:17])[CH3:16]Komponenten
3
Versuchsvorschrift
(R)—N-(2-tert-butyl-1-(2,3-dihydroxypropyl)-1H-indol-5-yl)-1-(3,4-dihydroxyphenyl)cyclopropanecarboxamide was prepared using an experimental procedure similar to Example 72 from 1-(3,4-dihydroxyphenyl)cyclopropanecarboxylic acid and 2-tert-butyl-5-nitro-1H-indole.
Quellen und Nachweise
- ORD-Eintrag
- ord-3813511059fe4418bd1957486d8083bc
- Quelldatensatz