2-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)- → alpha-Cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(-2-(isopropoxyimino)propyl)cyclopropanecarboxylat

HRID 1856585Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1856585
[CH3:1][C:2]1([CH3:31])[C@@H:4]([CH2:5][C:6](=[N:8][O:9][CH2:10][CH:11](C)C)[CH3:7])[C@H:3]1[C:14]([O:16][CH2:17][C:18]1[CH:23]=[CH:22][CH:21]=[C:20]([O:24][C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[CH:19]=1)=[O:15].CC1(C)[C@@H](C[C:37](=[N:39]OCC2CC2)C)[C@H]1C(OC(C#N)C1C=CC=C(OC2C=CC=CC=2)C=1)=O.[CH3:65]C1(C)[C@@H](CC(=NOCC2CCC2)C)[C@H]1C(OC(C#N)C1C=CC=C(OC2C=CC=CC=2)C=1)=O.C(C(O)C1C=CC=C(OC2C=CC=CC=2)C=1)#C.C1(=O)N(CO)C(=O)C2CCCCC1=2.ClC1C=CC=C(Cl)C=1CO.CC1C(O)CC(=O)C=1CC=C>>[CH3:1][C:2]1([CH3:31])[C@@H:4]([CH2:5][C:6](=[N:8][O:9][CH:10]([CH3:65])[CH3:11])[CH3:7])[C@H:3]1[C:14]([O:16][CH:17]([C:37]#[N:39])[C:18]1[CH:23]=[CH:22][CH:21]=[C:20]([O:24][C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[CH:19]=1)=[O:15]

Komponenten

8

Edukt 7

HCID 110832-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)-HCID 27156Benzenemethanol, 2,6-dichloro-HCID 78597N-(Hydroxymethyl)-3,4,5,6-tetrahydrophthalimideHCID 129190923-Phenoxy-alpha-ethynylbenzylalcoholHCID 544994723-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(isobutoxyimino)propyl)cyclopropanecarboxylateHCID 86737170alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclopropylmethoxyimino)propyl)cyclopropanecarboxylateHCID 86737171alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclobutylmethoxyimino)propyl)cyclopropanecarboxylate

Produkt 1

HCID 53742917alpha-Cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(-2-(isopropoxyimino)propyl)cyclopropanecarboxylat

Versuchsvorschrift

Following procedures similar to Embodiment II above: α-cyano-3-phenoxybenzyl (1R,cis)-2,2-diemthyl-3-(2-(neopentoxyimino)propyl)-cyclopropanecarboxylate, 3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(isobutoxyimino)propyl)cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclopropylmethoxyimino)propyl)cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclobutylmethoxyimino)propyl)cyclopropanecarboxylate are prepared as well as the corresponding esters in the racemic and (1R,trans) form and similar esters with other alcohols: α-ethynyl-3-phenoxybenzyl alcohol, 3,4,5,6-tetrahydrophthalimidomethyl alcohol, 2,6-dichlorobenzyl alcohol, 2-chloro-4-phenyl-2-butenl-ol and allethrolone.

Quellen und Nachweise

ORD-Eintrag
ord-b7cab9a64b8841d8b72ae73287c6d060
Quelldatensatz
uspto-grants-1980_08
Patentnummer
US04219563

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