3-Methyl-2-nonen-1-ol → 3-Methylnonan-1-ol
Reaktionsgleichung
[CH3:1][C:2]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])=[CH:3][CH2:4][OH:5]>[Ni]>[CH3:1][CH:2]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:3][CH2:4][OH:5]Komponenten
3
Edukt 1
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
52 G. of 3-methyl-2-nonen-1-ol were hydrogenated for 4 hours in the presence of Raney nickel catalyst at an initial pressure of 50 pounds per square inch until the theoretical amount of hydrogen was consumed. The hydrogenated material was fractionated through a 1/2 foot Vigreux column. 48.6 G. distilled at 108° C. under 10 mm. pressure, representing the desired 3-methylnonan-1-ol. The product had a refractive index at 20° C. of 1.4384. There was a residue of 3.4 g.
Aufarbeitung
- customat an initial pressure of 50 pounds per square inch until the theoretical amount of hydrogen was consumed
- distillationdistilled at 108° C. under 10 mm
- customat 20° C.
Quellen und Nachweise
- ORD-Eintrag
- ord-8726b0984a3e4b10aa28488bd49b18ef
- Quelldatensatz
- uspto-grants-1979_09
- Patentnummer
- US04168248
Notizen zur Reaktion
Wird geladen…