Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Ammonium bisulfate | HCID 24655 | — |
| Edukt | Sulfate, hydrogen | HCID 61778 | — |
| Edukt | Disulfate | HCID 177717 | — |
| Edukt | Pyrosulfuric acid, diammonium salt | HCID 11960345 | — |
| Lösungsmittel | Water | HCID 962 | — |
| Lösungsmittel | Ammonium Sulfate | HCID 6097028 | — |
| Produkt | Sulfuric Acid | HCID 1118 | — |
| Produkt | Ammonium Sulfate | HCID 6097028 | — |
Reaktionsschritte
At the conclusion of the thermal decomposition reaction, solids or molten liquid comprising the decomposition product are removed from the reactor or allowed to cool in the reactor. In either case, water is added to the decomposition product to produce a second stream. With ammonium sulfate as the primary compound in the ammonium sulfate (first) stream, the addition of water converts preferably all or most of the ammonium pyrosulfate which may be present to ammonium bisulfate. With other sulfate salts present in the ammonium sulfate stream, the corresponding pyrosulfate salts, if present, are converted into bisulfate salts. Without wishing to be bound by theory, when water is added to the decomposition product, salts may be formed in equilibrium with ammonium sulfate and sulfuric acid.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patentnummer | US07632479B2 |
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| Quelldatensatz | uspto-grants-2009_12 |
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| ORD ID | ord-0ba94b4fd1094b1783da523621a7df0d |
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| Quellennotiz | uspto-grants-2009_12 |
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