Carbon Tetrachloride → 1,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[3,3-dichloro-2-(4-trifluoromethyl-phenoxymethyl)-allyloxy]-benzene

HRID 1869147Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1869147
C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[C:20](Cl)(Cl)([Cl:22])[Cl:21].[Cl:25][C:26]1[CH:47]=[C:46]([O:48][CH2:49][CH:50]=[C:51]([Cl:53])[Cl:52])[CH:45]=[C:44]([Cl:54])[C:27]=1[O:28][CH2:29][C:30](=O)[CH2:31][O:32][C:33]1[CH:38]=[CH:37][C:36]([C:39]([F:42])([F:41])[F:40])=[CH:35][CH:34]=1>C(#N)C>[Cl:25][C:26]1[CH:47]=[C:46]([O:48][CH2:49][CH:50]=[C:51]([Cl:52])[Cl:53])[CH:45]=[C:44]([Cl:54])[C:27]=1[O:28][CH2:29][C:30]([CH2:31][O:32][C:33]1[CH:34]=[CH:35][C:36]([C:39]([F:42])([F:41])[F:40])=[CH:37][CH:38]=1)=[C:20]([Cl:22])[Cl:21]

Komponenten

5

Edukt 3

HCID 5943Carbon TetrachlorideHCID 11776TriphenylphosphineHCID 86613082HCID 86613082, Verbindung

Produkt 1

HCID 866130861,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[3,3-dichloro-2-(4-trifluoromethyl-phenoxymethyl)-allyloxy]-benzene

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6342AcetonitrileLösungsmittel

Versuchsvorschrift

312 mg of triphenylphosphine, 183 mg of carbon tetrachloride and 200 mg of 1-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-3-(4-trifluoromethyl-phenoxy)-propan-2-one are stirred in 3 ml of acetonitrile for 24 hours at 55° C. The reaction mixture is concentrated and the residue is purified over silica gel. The title compound is obtained.

Aufarbeitung

  1. concentrationThe reaction mixture is concentrated
  2. customthe residue is purified over silica gel

Quellen und Nachweise

ORD-Eintrag
ord-7bae7ae803fa4315b91414a54d8fdc88
Quelldatensatz
uspto-grants-2009_12
Patentnummer
US07638514B2

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