Phenylisohexanol → (E)-3(2-Hydroxy-5-methyl-phenyl)-acrylic acid 3-methyl-5-phenyl-pentyl ester

HRID 1870580Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1870580
[CH3:1][CH:2]([CH2:18][CH2:19][C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[CH2:3][CH2:4][O:5][C:6](=[O:17])[CH:7]=[CH:8][C:9]1[CH:14]=[C:13]([CH3:15])[CH:12]=[CH:11][C:10]=1[OH:16].C(OC(=O)C=CC1C=C(C)C=CC=1O)C.CC(CCC1C=CC=CC=1)CCO>>[CH3:1][CH:2]([CH2:18][CH2:19][C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[CH2:3][CH2:4][O:5][C:6](=[O:17])/[CH:7]=[CH:8]/[C:9]1[CH:14]=[C:13]([CH3:15])[CH:12]=[CH:11][C:10]=1[OH:16]

Komponenten

4

Edukt 3

HCID 108312PhenylisohexanolHCID 538004553-(2-Hydroxy-5-methyl-phenyl)-acrylic acid 3-methyl-5-phenyl-pentyl esterHCID 538322453-(2-Hydroxy-5-methyl-phenyl)-acrylic acid ethyl ester

Produkt 1

HCID 68523369(E)-3(2-Hydroxy-5-methyl-phenyl)-acrylic acid 3-methyl-5-phenyl-pentyl ester

Versuchsvorschrift

According to the same procedure, 3-(2-hydroxy-5-methyl-phenyl)-acrylic acid 3-methyl-5-phenyl-pentyl ester was prepared from 3-(2-hydroxy-5-methyl-phenyl)-acrylic acid ethyl ester, 3-methyl-5-phenyl-pentanol and tetraisopropyl-o-titanate.

Quellen und Nachweise

ORD-Eintrag
ord-6004b6c2cb414f35a52b085f0433eee4
Quelldatensatz
uspto-grants-2000_08
Patentnummer
US06096918

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