2-Hydroxy-11-cycloeicosenone → 2-Hydroxycyclooctadecanone

HRID 1883291

Reaktionsgleichung

Reaktionsgleichung von HRID 1883291
[OH:1][CH:2]1[CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH:13]=[CH:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]CC[C:3]1=[O:22].OC1CCCCCCC=CCCCCCCCCC1=O>>[OH:1][CH:2]1[CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][C:3]1=[O:22]

Komponenten

3

Edukt 2

HCID 673128522-Hydroxy-11-cycloeicosenoneHCID 696496782-Hydroxy-9-cyclooctadecenone

Produkt 1

HCID 98788872-Hydroxycyclooctadecanone

Versuchsvorschrift

2-Hydroxy-11-cycloeicosenone of Synthesis Example 7 was replaced by 2-hydroxy-9-cyclooctadecenone (1.0 g, 3.54 mmol), and a hydrogenation and subsequent treatment were performed under the same conditions as in Synthesis Example 7, to yield 1.0 g of 2-hydroxycyclooctadecanone (quantitative yield).

Aufarbeitung

  1. customa hydrogenation and subsequent treatment were performed under the same conditions as in Synthesis Example 7

Quellen und Nachweise

ORD-Eintrag
ord-b77a471df5e74655ac77e43502bce19d
Quelldatensatz
uspto-grants-2004_07
Patentnummer
US06759557B2

Verknüpfte Notizen

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