tert-Butanol → Tert-butyl 3-oxo-11-eicosenoate

HRID 1903527Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1903527
[OH:1][C:2](=[C:20]1[C:25](=[O:26])[O:24][C:23]([CH3:28])([CH3:27])OC1=O)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]=[CH:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[C:30](O)(C)(C)C>>[O:1]=[C:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]=[CH:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[CH2:20][C:25]([O:24][C:23]([CH3:27])([CH3:28])[CH3:30])=[O:26]

Komponenten

3

Edukt 2

HCID 6386tert-ButanolHCID 704466915-(1-Hydroxy-9-octadecenylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione

Produkt 1

HCID 54459894Tert-butyl 3-oxo-11-eicosenoate

Versuchsvorschrift

Starting from 5-(1-hydroxy-9-octadecenylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione (18 g) and tert-butyl alcohol (200 ml), tert-butyl 3-oxo-11-eicosenoate was obtained as an oil according to a similar manner to that of Preparation A-2(2).

Quellen und Nachweise

ORD-Eintrag
ord-ed92439fb4c744c9aa17a63bbeb6cd84
Quelldatensatz
uspto-grants-1984_03
Patentnummer
US04436726

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