3-(3-Phenyl-1-propenyl)aniline → 3-(3-Phenylpropyl)aniline

HRID 1903652

Reaktionsgleichung

Reaktionsgleichung von HRID 1903652
[C:1]1([CH2:7][CH:8]=[CH:9][C:10]2[CH:11]=[C:12]([CH:14]=[CH:15][CH:16]=2)[NH2:13])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>C(O)C.[C].[Pd]>[C:1]1([CH2:7][CH2:8][CH2:9][C:10]2[CH:11]=[C:12]([CH:14]=[CH:15][CH:16]=2)[NH2:13])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Komponenten

4

Edukt 1

HCID 540429893-(3-Phenyl-1-propenyl)aniline

Produkt 1

HCID 4273073-(3-Phenylpropyl)anilineAusbeute 92 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 178418390HCID 178418390, VerbindungKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

A solution of 3-(3-phenyl-1-propenyl)aniline (3.6 g) in 50 ml of ethanol was subjected to catalytic reduction using 1 g of 10% palladium-carbon. After removal of the catalyst by filtration, the solvent was removed under reduced pressure. The residue was distilled under reduced pressure to give 3.3 g of 3-(3-phenylpropyl)aniline (yield, 92%). B.P. 122°-126° C./0.08 mmHg.

Aufarbeitung

  1. customAfter removal of the catalyst
  2. filtrationby filtration
  3. customthe solvent was removed under reduced pressure
  4. distillationThe residue was distilled under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-14973120f72e4eb5953e84b360c0baf4
Quelldatensatz
uspto-grants-1984_03
Patentnummer
US04437880

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