HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
N-bromobutanimide → 1-(Bromomethyl)-4-(phenylsulfonyl)benzene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | N-bromobutanimide | HCID 67184 | — |
| Edukt | p-Tolyl phenylsulphone | HCID 86739317 | — |
| Katalysator | Benzoyl Peroxide | HCID 7187 | — |
| Lösungsmittel | Carbon Tetrachloride | HCID 5943 | — |
| Produkt | 1-(Bromomethyl)-4-(phenylsulfonyl)benzene | HCID 264100 | 171,6% |
Reaktionsschritte
A solution of p-tolyl phenylsulphone (20 g) in refluxing CCl4 (400 ml) containing dibenzoyl peroxide (0.4 g) was treated with N-bromosuccinimide (15.3 g) in portions rapidly. The mixture was heated under reflux for 30 min., filtered whilst hot and the filtrate allowed to cool. Evaporation gave the title compound (26.8 g), m.p. (103°-104°.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04438112 |
| Quelldatensatz | uspto-grants-1984_03 |
| ORD ID | ord-95cb870c4edd41fd92c92ca6e0141477 |
| Quellennotiz | uspto-grants-1984_03 |